An Introduction to Petrochemicals
石油化工產(chǎn)品概述
1. The petroleum era was ushered in by the 1859 finding at Titusville, Pennsylvania, but the flourishing of chemicals from petroleum has been only since the early twentieth century. Natural gas and petroleum are in fact our chief sources of hydrocarbons. Natural gas is quite variable in composition, but the major constituent （>60%） is methane. Other components are the homologous alkanes, ethane, propane, and higher hydrocarbons. In terms of volume, most of the natural gas produced is used for fuel, although a substantial amount is used as raw material for the synthesis of various types of chemicals.
1、1859賓西法尼亞洲Titusville地區(qū)鉆出油井，開創(chuàng)了石油時(shí)代。但從石油中成功地提取化學(xué)產(chǎn)品，則直到20世紀(jì)早期才開始。實(shí)際上,天然氣和石油是我們碳?xì)浠衔锏闹饕獊?lái)源。天然氣在成分上不大穩(wěn)定，但主要成分（60%）是甲烷。，其他組分有同系烷、乙烷、丙烷以及高分子碳?xì)浠衔�。從�?shù)量看，盡管有相當(dāng)數(shù)量的天然氣用作各種合成化合物的原料，但所生產(chǎn)的大多數(shù)天然氣用作燃料。
2. The chemical industry depends very heavily on petroleum, natural gas, and natural gas liquids as sources of raw materials. It is likely that in excess of 90% of the literally thousands of different basic organic chemicals employed today are derived from these sources.
2、化學(xué)工業(yè)的原材料來(lái)源嚴(yán)重依賴石油、天然氣和液態(tài)天然氣。當(dāng)今所應(yīng)用的上千種不同的基本有機(jī)化學(xué)產(chǎn)品中很可能有超過(guò)90%的產(chǎn)品來(lái)自這些資源。
3. The petrochemical industry has grown with the petroleum industry and is considered by some to be a mature industry. However, as is the case with the latest trends in changing crude oil types, it must also evolve to meet changing technological needs.
3、石油化學(xué)工業(yè)是隨著石油工業(yè)發(fā)展起來(lái)的，而且有人認(rèn)為已是一個(gè)成熟的工業(yè)部門。然而，從原油類型變化的最新趨勢(shì)來(lái)看，石油化學(xué)工業(yè)同樣需要進(jìn)一步發(fā)展以適應(yīng)技術(shù)發(fā)展的需要。
4. The manufacture of chemicals or chemical intermediates from petroleum and natural gas constituents is an excellent example of the conversion of such materials to more valuable products. The individual chemicals made from petroleum and natural gas are numerous and include industrial chemicals, household chemicals, fertilizers, and paints, as well as intermediates for the manufacture of products, such as synthetic rubber and plastics.
4、從石油和天然氣組分中生產(chǎn)化學(xué)產(chǎn)品或化學(xué)中間產(chǎn)品極好地證明了這些物質(zhì)能夠轉(zhuǎn)換成更有價(jià)值的產(chǎn)品。從石油和天然氣提取的單個(gè)化學(xué)產(chǎn)品數(shù)量眾多；包括工業(yè)產(chǎn)品、家庭用品、化肥、油漆、以及用于生產(chǎn)其他產(chǎn)品的中間產(chǎn)品，如合成橡膠和塑料。
5. The processing of petroleum hydrocarbon to yield materials that are, essentially, the building blocks of other chemicals industries, is now very extensive.
5、石油碳?xì)浠衔锿ㄟ^(guò)加工所生產(chǎn)的物質(zhì)，基本上是其他化學(xué)工業(yè)的預(yù)制品，這種加工目前范圍十分廣泛。
6. Petrochemicals are generally chemical compounds derived from petroleum either by direct manufacture or by indirect manufacture as by-products from the variety of processes that are used during the refining of petroleum. Gasoline, kerosene, fuel oils, Lubricating oils, waxes, asphalts, and the like are excluded from the definition of petrochemicals, since they are not, in the true sense, chemical compounds but are in fact intimate mixtures of hydrocarbons.
6、石化產(chǎn)品一般指直接或間接地從石油中提煉的化合物，這些化合物往往是石油煉制各種過(guò)程中產(chǎn)生的副產(chǎn)品。汽油、煤油、燃料油、潤(rùn)滑油、石蠟、瀝青以及諸如此類的產(chǎn)品不屬于石化產(chǎn)品。因?yàn)�，從�?yán)格意義上說(shuō)，它們不是化合物，而是烴類的均質(zhì)混合物。
7. The classification of materials such as petrochemicals is used to indicate the source of the chemical compounds, but it should be remembered that many common petrochemicals can be made from other sources, and the terminology is therefore a matter of source identification.
7、象“石化產(chǎn)品”這樣的物質(zhì)分類用來(lái)表明化合物的來(lái)源。但應(yīng)記住，許多我們所熟知的石化產(chǎn)品也可以通過(guò)其他途徑生產(chǎn)，因而這一名稱只是用來(lái)識(shí)別原料。
8. The starting materials for the petrochemical industry are obtained from crude petroleum in one of two general ways. They may be present in the virgin petroleum and as such, are isolated by physical methods, such as distillation or solvent extraction. On the other hand, they may be present in trace amounts and are synthesized during the refining operations. In fact, unsaturated hydrocarbons, which are not usually present in virgin petroleum, are nearly always manufactured as intermediates during the various refining sequences.
8、石化工業(yè)的初始原料大概通過(guò)一到兩種方法從原油中提取。這些原料物質(zhì)，也許本身就存在于原油當(dāng)中，因此通過(guò)物理方法加以分離，如蒸餾和溶取。同時(shí)，這些物質(zhì)也可能因含量低而在煉制作業(yè)中生成了合成物。實(shí)際上，原油中一般不存在非飽和烴，幾乎所有的非飽和烴都是在各種煉制過(guò)程中作為中間產(chǎn)品而產(chǎn)生的。
9. The manufacture of chemicals from petroleum is based on the ready response of the various compound types to basic chemical reactions, such as oxidation, halogenation, nitration, dehydrogenation, addition, polymerization, and alkylation. The low-molecular-weight paraffins and olefins, as found in natural gas and refinery gases, and the simple aromatic hydrocarbons have so far been of the most interest because it is these individual species that can readily be isolated and dealt with. A wide range of compounds is possible, many are being manufactured, and we are now progressing the stage in which a sizable group of products is being prepared from the heavier fractions of petroleum. For example, the various reactions of petroleum heavy ends, in particular the asphaltenes, indicate that these materials may be regarded as chemical entities and are able to participate in numerous chemical or physical conversions to, perhaps, more useful materials. The overall effect of these modifications is the production of materials that either afford good-grade aromatic cokes comparatively easily or the formation of products bearing functional groups that may be employed as a nonfuel material.
9、從石油生產(chǎn)化學(xué)品的依據(jù)是各種類型的化合物對(duì)各種基本的化學(xué)作用感應(yīng)迅速，如氧化作用、鹵化作用、硝化作用、脫氫作用、添加作用、聚合作用和烷基化作用。迄今為止，人們最感興趣的是從天然氣和煉廠氣中所得到的低分子量石蠟和稀烴，以及簡(jiǎn)單芳烴，因?yàn)檫@些物質(zhì)能夠進(jìn)行迅速分離和處理。大量化合物都有望得到、其中許多化合物正在生產(chǎn)。目前我們正在探索如何從石油的重質(zhì)餾分中提煉數(shù)量可觀的產(chǎn)品。比如，石油重質(zhì)尾部餾分，尤其是瀝青質(zhì)的各種反應(yīng)表明這些物質(zhì)可以看成化學(xué)本質(zhì)，也許能夠通過(guò)各種化學(xué)和物理反應(yīng)轉(zhuǎn)變成更有價(jià)值的產(chǎn)品。這些變化的總體效應(yīng)是，所生產(chǎn)的物質(zhì)，或者能夠相對(duì)容易地提供高品質(zhì)芳焦，或者能夠形成功能族產(chǎn)品，用作非燃料材料。
10. For example, the sulfonated and sulfomethlated materials and their derivatives have satisfactorily undergone tests as drilling mud thinners, and the results are comparable to those obtained with commercial mud thinners. In addition, these compounds may also find use as emulsifiers for the in situ recovery of heavy oils. There are also indications that these materials and other similar derivatives of the asphaltenes, especially those containing such functions as carboxylic or hydroxyl, readily exchange cations and could well compete with synthetic zeolites. Other uses of the hydroxyl derivatives and / or the chloroasphaltenes include high-temperature packings or heat transfer media.
10、比如，將磺化物質(zhì)、磺甲基化物質(zhì)及其衍生物作為鉆井泥漿稀料進(jìn)行測(cè)試，效果令人滿意，其應(yīng)用效果可以同商業(yè)泥漿稀料相媲美。此外，這些化合物也可用作重油初采的乳化劑。另有跡象表明，這些物質(zhì)和瀝青質(zhì)的其它類似衍生物，尤其是具有諸如羧基和羥基功能的物質(zhì)，能夠迅速地交換陽(yáng)離子，并且同沸石形成有力抗衡。羥基和/或含氯瀝青的衍生物的其他用途包括用作高溫包裝材料和熱傳遞介質(zhì)。
11. Reactions incorporating nitrogen and phosphorus into the asphaltenes are particularly significant at a time when the effects on the environment of many materials containing these elements are receiving considerable attention. Various measures have been and will be taken to release such effects.
11、將氮?dú)夂土谆旌铣蔀r青的化學(xué)反應(yīng)尤為重要，因?yàn)楹羞@些元素的物質(zhì)對(duì)環(huán)境造成的影響正受到嚴(yán)重關(guān)注。人們已經(jīng)且還要采取各種措施來(lái)減少這些影響。
12. Nevertheless, the main objective in producing chemicals from petroleum is the formation of a variety of well-defined chemical compounds that are the basis of the petrochemical industry. It must be remembered, however, that ease of separation of a particular compound from petroleum does not guarantee its use as a petrochemical building block. Other parameters, particularly the economics of the reaction sequences, including the costs of the reactant equipment, must also be taken into consideration.
12、不過(guò)，從石油生產(chǎn)化學(xué)制品的主要目的在于，生產(chǎn)出大量具有明確界定的化合物，以奠定石化工業(yè)的基礎(chǔ)。但是必須清楚，如果某種化合物能夠容易地從石油中分離出來(lái)，并不表明它一定就是石化產(chǎn)品的預(yù)制品。其它因素，尤其是生產(chǎn)這些化合物的經(jīng)濟(jì)因素，包括反應(yīng)設(shè)備的成本，必須考慮在內(nèi)。
